diff --git a/pyiceberg/io/pyarrow.py b/pyiceberg/io/pyarrow.py
index 1077f41f6a..f74a116e6e 100644
--- a/pyiceberg/io/pyarrow.py
+++ b/pyiceberg/io/pyarrow.py
@@ -1435,6 +1435,13 @@ def primitive(self, primitive: pa.DataType) -> PrimitiveType:
         elif pa.types.is_null(primitive):
             # PyArrow null type (pa.null()) is converted to Iceberg UnknownType
             # UnknownType can be promoted to any primitive type in V3+ tables per the Iceberg spec
+            if self._format_version < 3:
+                field_path = ".".join(self._field_names) if self._field_names else "<root>"
+                raise ValueError(
+                    "Null type (pa.null()) is not supported in Iceberg format version "
+                    f"{self._format_version}. Field: {field_path}. "
+                    "Use a concrete type (string, int, boolean, etc.) or set format-version=3."
+                )
             return UnknownType()
         elif isinstance(primitive, pa.UuidType):
             return UUIDType()
diff --git a/tests/catalog/test_base.py b/tests/catalog/test_base.py
index 42702c8c2b..91f13b426e 100644
--- a/tests/catalog/test_base.py
+++ b/tests/catalog/test_base.py
@@ -207,6 +207,16 @@ def test_convert_schema_if_needed(
     assert expected == catalog._convert_schema_if_needed(schema)
 
 
+def test_convert_schema_if_needed_rejects_null_type(catalog: InMemoryCatalog) -> None:
+    schema = pa.schema([pa.field("n1", pa.null())])
+    with pytest.raises(ValueError) as exc_info:
+        catalog._convert_schema_if_needed(schema)
+    message = str(exc_info.value)
+    assert "Null type" in message
+    assert "n1" in message
+    assert "format-version=3" in message
+
+
 def test_create_table_pyarrow_schema(catalog: InMemoryCatalog, pyarrow_schema_simple_without_ids: pa.Schema) -> None:
     catalog.create_namespace(TEST_TABLE_NAMESPACE)
     table = catalog.create_table(